Innenrücktitelbild: Site‐Selective Photo‐Crosslinking of Stilbene Pairs in a DNA Duplex Mediated by Ruthenium Photocatalyst (Angew. Chem. 14/2024)

Site‐selective photocrosslinking of DNA duplex was achieved in the Research Article (e202319516) by Hiromu Kashida, Hiroyuki Asanuma et al. A ruthenium complex on a triplex‐forming oligonucleotide effectively catalyzed [2+2] photocycloaddition of stilbene moieties in a DNA duplex under visible light...

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Veröffentlicht in:	Angewandte Chemie 2024-04, Vol.136 (14), p.n/a
Hauptverfasser:	Kashida, Hiromu, Azuma, Hidenori, Sotome, Hikaru, Miyasaka, Hiroshi, Asanuma, Hiroyuki
Format:	Artikel
Sprache:	eng
Schlagworte:	Crosslinking Deoxyribonucleic acid DNA Energy transfer Oligonucleotides Ruthenium Ruthenium compounds Stilbene
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Zusammenfassung:	Site‐selective photocrosslinking of DNA duplex was achieved in the Research Article (e202319516) by Hiromu Kashida, Hiroyuki Asanuma et al. A ruthenium complex on a triplex‐forming oligonucleotide effectively catalyzed [2+2] photocycloaddition of stilbene moieties in a DNA duplex under visible light. Since the reaction proceeds via triplet–triplet energy transfer, the reaction exhibited excellent site selectivity.
ISSN:	0044-8249 1521-3757
DOI:	10.1002/ange.202404237