Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines

Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines

Complexes of rhodium(II) acetate with 2 H -azirines were obtained for the first time. The 1 : 2 complexes were characterized using 1 H and 13 C NMR, IR, and UV spectroscopy and high-resolution mass spectrometry. The structure of Rh 2 (OAc) 4 complex with two 3-(4-methoxyphenyl)-2 H -azirine molecule...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of general chemistry 2024, Vol.94 (Suppl 1), p.S47-S52
Hauptverfasser: Grishin, A. V., Filippov, I. P., Rostovskii, N. V.
Format: Artikel
Sprache:eng
Schlagworte:
Acetates
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Heterocyclic compounds
Infrared spectroscopy
Mass spectrometry
Nitrogen
NMR
Nuclear magnetic resonance
Rhodium
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Complexes of rhodium(II) acetate with 2 H -azirines were obtained for the first time. The 1 : 2 complexes were characterized using 1 H and 13 C NMR, IR, and UV spectroscopy and high-resolution mass spectrometry. The structure of Rh 2 (OAc) 4 complex with two 3-(4-methoxyphenyl)-2 H -azirine molecules was studied by X-ray diffraction analysis. In crystal, the molecule of this complex belongs to the C i point group.
ISSN:1070-3632
1608-3350
DOI:10.1134/S107036322414007X