Chemical Stability of the CsZr2(PO4)3 Phosphate with the Kosnarite Structure in Various Environments
— The CsZr 2 (PO 4 ) 3 phosphate isostructural with the mineral kosnarite has been prepared via sol–gel synthesis at 900°C, and ceramics based on this phosphate have been produced by spark plasma sintering. The relative density of the ceramics has been determined to be 75.5%. The chemical stability...
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Veröffentlicht in: | Inorganic materials 2023-09, Vol.59 (9), p.1019-1025 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | —
The CsZr
2
(PO
4
)
3
phosphate isostructural with the mineral kosnarite has been prepared via sol–gel synthesis at 900°C, and ceramics based on this phosphate have been produced by spark plasma sintering. The relative density of the ceramics has been determined to be 75.5%. The chemical stability of the ceramic materials has been assessed at 90°C in static mode in distilled and mineral water, weakly acidic solution, and weakly alkaline solution. The minimum rates of Cs leaching were ~10
–5
to 10
–4
g/(cm
2
day). We have assessed the effect of contact medium on the mechanism of cesium leaching from the CsZr
2
(PO
4
)
3
ceramics. |
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ISSN: | 0020-1685 1608-3172 |
DOI: | 10.1134/S0020168523090029 |