Spectroscopic investigation of Dy2O3 doped B2O3-SiO2-Na2O-K2O glass for W-LEDs and laser application
B 2 O 3 –SiO 2 –Na 2 O–K 2 O–Dy 2 O 3 glasses were prepared and study for their spectroscopic and physical properties in detail. The density of present BSNK glasses increases with an increase in Dy-ions concentration. Moreover, Dy-ion concentration ( N ) and field Strength also show an increasing tr...
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Veröffentlicht in: | Indian journal of physics 2024-04, Vol.98 (4), p.1471-1480 |
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Hauptverfasser: | , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | B
2
O
3
–SiO
2
–Na
2
O–K
2
O–Dy
2
O
3
glasses were prepared and study for their spectroscopic and physical properties in detail. The density of present BSNK glasses increases with an increase in Dy-ions concentration. Moreover, Dy-ion concentration (
N
) and field Strength also show an increasing trend. Absorption spectra exhibit eight characteristic peaks in Vis and NIR region. The trend in JO parameters is
Ω
2
>
Ω
6
>
Ω
4
for the BSNKDy1.5 glass sample with a higher value of
Ω
2
. Six transitions are observed in the excitation spectra (300–500 range and
λ
em
= 573 nm) of the BSNKDy samples. Emission cross section (
σ
p
(
λ
p
)) for
4
F
9/2
→
6
H
13/2
transition has the highest value among other transition of NSNKD1.5 glass. The quantum efficiency for BSNKDY1.5 glass is 55%. The CIE coordinates and CCT-value for BSNKDy glasses are (0.37, 0.41) and 4461 K, respectively. Hence, these are suitable for high-gain, continuous low-threshold laser action and W-LEDs.
Graphical abstract |
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ISSN: | 0973-1458 0974-9845 |
DOI: | 10.1007/s12648-023-02954-y |