Structure, Electrical Resistivity and Superconductivity of Low- alloyed γ-U Phase Retained to Low Temperatures by Means of Rapid Cooling

The γ-U phase alloys can be retained down to low temperatures with less required alloying concentration by using the splat-cooling technique with a cooling rate better than 10^6 K/s. Doping with 15 at.% Mo, Pt, Pd, Nb leads to a stabilization of the cubic γ-U phase, while it requires much higher Zr...

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Veröffentlicht in:Acta metallurgica sinica : English letters 2016-04, Vol.29 (4), p.388-398
Hauptverfasser: Krupska, M., Kim-Ngan, N.-T. H., Sowa, S., Paukov, M., Tkach, I., Drozdenko, D., Havela, L., Tarnawski, Z.
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Sprache:eng
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Zusammenfassung:The γ-U phase alloys can be retained down to low temperatures with less required alloying concentration by using the splat-cooling technique with a cooling rate better than 10^6 K/s. Doping with 15 at.% Mo, Pt, Pd, Nb leads to a stabilization of the cubic γ-U phase, while it requires much higher Zr concentrations (≥30 at.% Zr). All U-T splats become superconducting with Tc in the range of 0.61-2.11 K. A good agreement of the experimentally observed specific-heat jump at Tc with that from BCS theory prediction was obtained for U-15 at.% Mo consisting of the γ-U phase with an ideal bcc A2 structure.
ISSN:1006-7191
2194-1289
DOI:10.1007/s40195-016-0400-7