Structure, Electrical Resistivity and Superconductivity of Low- alloyed γ-U Phase Retained to Low Temperatures by Means of Rapid Cooling
The γ-U phase alloys can be retained down to low temperatures with less required alloying concentration by using the splat-cooling technique with a cooling rate better than 10^6 K/s. Doping with 15 at.% Mo, Pt, Pd, Nb leads to a stabilization of the cubic γ-U phase, while it requires much higher Zr...
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Veröffentlicht in: | Acta metallurgica sinica : English letters 2016-04, Vol.29 (4), p.388-398 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The γ-U phase alloys can be retained down to low temperatures with less required alloying concentration by using the splat-cooling technique with a cooling rate better than 10^6 K/s. Doping with 15 at.% Mo, Pt, Pd, Nb leads to a stabilization of the cubic γ-U phase, while it requires much higher Zr concentrations (≥30 at.% Zr). All U-T splats become superconducting with Tc in the range of 0.61-2.11 K. A good agreement of the experimentally observed specific-heat jump at Tc with that from BCS theory prediction was obtained for U-15 at.% Mo consisting of the γ-U phase with an ideal bcc A2 structure. |
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ISSN: | 1006-7191 2194-1289 |
DOI: | 10.1007/s40195-016-0400-7 |