Fe3C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium

The emergence of non‐precious metal‐based robust and economic bifunctional oxygen electrocatalysts for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is crucial for the rational design of commercial rechargeable Zn‐air batteries (RZAB) with safe energy conversion and storage systems. Herein, a facile strategy to fabricate a cost‐efficient, bifunctional oxygen electrocatalyst Fe3C/Fe decorated N doped carbon (FeC‐700, the catalyst prepared at carbinization temperature of 700 °C) with a unique structure has been developed by carbonization of a single source precursor, tetrabutylammonium tetrachloroferrate(III) complex. The ORR and OER activity revealed excellent performance (ΔE=0.77 V) of the FeC‐700 electrocatalyst, comparable to commercial Pt/C and RuO2, respectively. The designed temperature‐tuneable structure provided sufficiently accessible active sites for the continuous passage of electrons by shortening the mass transfer pathway, leading to extremely durable electrocatalysts with high ECSA and amazing charge transfer performance. Remarkably, the assembled Zn‐air batteries with the FeC‐700 catalyst as the bifunctional air electrode delivers gratifying charging‐discharging ability with an impressive power density of 134 mW cm−2 with a long lifespan, demonstrating prodigious possibilities for practical application. A facile strategy to fabricate a cost‐efficient Fe3C/Fe decorated N doped carbon has been developed. The catalysts showed excellent ORR and OER activities. The assembled Zn‐air battery with the catalyst as the bifunctional air electrode delivers excellent charging‐discharging ability and power density.