New DySrAlO4 Compound Synthesis and Formation Process Correlations for LnSrAlO4 (Ln = Nd, Gd, Dy) Series

For the first time, DySrAlO 4 of K 2 NiF 4 -type structure was synthesized. The parameters of DySrAlO 4 elementary unit cell are determined as follows: a  = 0.368 (4) nm, c  = 1.229 (2) nm, V  = 0.166 (4) nm 3 . The research of the complex aluminates Ln SrAlO 4 ( Ln  = Nd, Gd, Dy) solid-state proces...

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Veröffentlicht in:Acta metallurgica sinica : English letters 2016-05, Vol.29 (5), p.450-456
1. Verfasser: Tugova, E. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:For the first time, DySrAlO 4 of K 2 NiF 4 -type structure was synthesized. The parameters of DySrAlO 4 elementary unit cell are determined as follows: a  = 0.368 (4) nm, c  = 1.229 (2) nm, V  = 0.166 (4) nm 3 . The research of the complex aluminates Ln SrAlO 4 ( Ln  = Nd, Gd, Dy) solid-state process demonstrated the change of the formation mechanism among Ln SrAlO 4 ( Ln  = Nd, Gd, Dy) series from DySrAlO 4 oxide. The performed analysis provided a possibility to realize why chemists couldn’t get DySrAlO 4 for a long period of time.
ISSN:1006-7191
2194-1289
DOI:10.1007/s40195-016-0407-0