New DySrAlO4 Compound Synthesis and Formation Process Correlations for LnSrAlO4 (Ln = Nd, Gd, Dy) Series
For the first time, DySrAlO 4 of K 2 NiF 4 -type structure was synthesized. The parameters of DySrAlO 4 elementary unit cell are determined as follows: a = 0.368 (4) nm, c = 1.229 (2) nm, V = 0.166 (4) nm 3 . The research of the complex aluminates Ln SrAlO 4 ( Ln = Nd, Gd, Dy) solid-state proces...
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Veröffentlicht in: | Acta metallurgica sinica : English letters 2016-05, Vol.29 (5), p.450-456 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | For the first time, DySrAlO
4
of K
2
NiF
4
-type structure was synthesized. The parameters of DySrAlO
4
elementary unit cell are determined as follows:
a
= 0.368 (4) nm,
c
= 1.229 (2) nm,
V
= 0.166 (4) nm
3
. The research of the complex aluminates
Ln
SrAlO
4
(
Ln
= Nd, Gd, Dy) solid-state process demonstrated the change of the formation mechanism among
Ln
SrAlO
4
(
Ln
= Nd, Gd, Dy) series from DySrAlO
4
oxide. The performed analysis provided a possibility to realize why chemists couldn’t get DySrAlO
4
for a long period of time. |
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ISSN: | 1006-7191 2194-1289 |
DOI: | 10.1007/s40195-016-0407-0 |