Metal-Organic Coordination Polymers of Cadmium Based on Anilate Ligands

New metal-organic coordination polymers (MOCPs) of cadmium(II) based on chelate-type ligands have been synthesized. The structural features of the obtained zigzag polymer derivatives [Cd(pQ)(1,2-PG)]⋅2DMF, [Cd(pQ)⋅2DMAA], [Cd(pQ)⋅2NMP], [Cd(pQ)(1,2-PG)]⋅2NMP, [Cd(CA)⋅2NMP], and [Cd(CA)(1,3-PG)]⋅2NMP...

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Veröffentlicht in:Crystallography reports 2023-12, Vol.68 (7), p.1099-1108
Hauptverfasser: Trofimova, O. Yu, Maleeva, A. V., Arsenyeva, K. V., Klimashevskaya, A. V., Cherkasov, A. V., Yakushev, I. A., Piskunov, A. V.
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Sprache:eng
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Zusammenfassung:New metal-organic coordination polymers (MOCPs) of cadmium(II) based on chelate-type ligands have been synthesized. The structural features of the obtained zigzag polymer derivatives [Cd(pQ)(1,2-PG)]⋅2DMF, [Cd(pQ)⋅2DMAA], [Cd(pQ)⋅2NMP], [Cd(pQ)(1,2-PG)]⋅2NMP, [Cd(CA)⋅2NMP], and [Cd(CA)(1,3-PG)]⋅2NMP (where pQ is the dianion of 2,5-di-hydroxy-3,6-di- tert -butyl- p -benzoquinone, CA is the dianion of chloranilic acid, 1,2-PG is 1,2-propanediol, 1,3-PG is 1,3-propanediol, DMF is N , N -dimethylformamide, DMAA is N , N -dimethylacetamide, NMP is N -methyl-2-pyrrolidone) are studied. The molecular and crystal structures of the synthesized MOCPs were established by X-ray diffraction analysis of single crystals.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774523600059