Metal-Organic Coordination Polymers of Cadmium Based on Anilate Ligands
New metal-organic coordination polymers (MOCPs) of cadmium(II) based on chelate-type ligands have been synthesized. The structural features of the obtained zigzag polymer derivatives [Cd(pQ)(1,2-PG)]⋅2DMF, [Cd(pQ)⋅2DMAA], [Cd(pQ)⋅2NMP], [Cd(pQ)(1,2-PG)]⋅2NMP, [Cd(CA)⋅2NMP], and [Cd(CA)(1,3-PG)]⋅2NMP...
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Veröffentlicht in: | Crystallography reports 2023-12, Vol.68 (7), p.1099-1108 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | New metal-organic coordination polymers (MOCPs) of cadmium(II) based on chelate-type ligands have been synthesized. The structural features of the obtained zigzag polymer derivatives [Cd(pQ)(1,2-PG)]⋅2DMF, [Cd(pQ)⋅2DMAA], [Cd(pQ)⋅2NMP], [Cd(pQ)(1,2-PG)]⋅2NMP, [Cd(CA)⋅2NMP], and [Cd(CA)(1,3-PG)]⋅2NMP (where pQ is the dianion of 2,5-di-hydroxy-3,6-di-
tert
-butyl-
p
-benzoquinone, CA is the dianion of chloranilic acid, 1,2-PG is 1,2-propanediol, 1,3-PG is 1,3-propanediol, DMF is
N
,
N
-dimethylformamide, DMAA is
N
,
N
-dimethylacetamide, NMP is
N
-methyl-2-pyrrolidone) are studied. The molecular and crystal structures of the synthesized MOCPs were established by X-ray diffraction analysis of single crystals. |
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ISSN: | 1063-7745 1562-689X |
DOI: | 10.1134/S1063774523600059 |