Organoboron-based multiple-resonance emitters: synthesis, structure-property correlations, and prospects

Boron-based multiple-resonance (MR) emitters exhibit the advantages of narrowband emission, high absolute photoluminescence quantum yield, thermally activated delayed fluorescence (TADF), and sufficient stability during the operation of organic light-emitting diodes (OLEDs). Thus, such MR emitters have been widely applied as blue emitters in triplet-triplet-annihilation-driven fluorescent devices used in smartphones and televisions. Moreover, they hold great promise as TADF or terminal emitters in TADF-assisted fluorescence or phosphor-sensitised fluorescent OLEDs. Herein we comprehensively review organoboron-based MR emitters based on their synthetic strategies, clarify structure-photophysical property correlations, and provide design guidelines and future development prospects. This review highlights organoboron-based multiple-resonance compounds' synthetic strategies classified as one-pot borylation, one-shot borylation, and late-stage functionalisation, and explores material structure-photophysical property correlations.