Performance Analysis of Triple‐Cation Mixed‐Halide Bifacial Perovskite Solar Cell with 17% Rear and 25% Front Efficiency

The goal of bifacial technology is to increase the efficiency of solar cells (SC) by capturing albedo sunlight and converting it to electrical energy. The use of triple‐cation mixed‐halide perovskite solar cells (PSC) has sparked a lot of curiosity and could be the potential for improved power conversion efficiency (PCE) associated with traditional PSCs. Herein, n–i–p‐configured triple‐cation mixed‐halide‐based bifacial PSC is studied using the SC capacitance simulator 1D tool. Through our simulation, the impact of thickness in electron and hole transport layers (ETL and HTLs), defect density, doping density, and the thickness of the light‐harvesting layer on the device performance is examined. With an optimal design, the device exhibits an absolutely staggering efficiency of 25.28% from the front side and around 17.19% from the rear. This cell, due to its high albedo absorption, linearly enhances the short‐circuit current; hence, it overcomes the classical current‐matching limit of ordinary PSCs. The proposed device FTO/TiO2/[Cs0.05(MA0.17FA0.83)0.95Pb(I0.83Br0.17)3]/CuSbS2 has a remarkable efficiency that increases linearly with albedo, making it very appealing for new, high‐efficiency solar applications. n–i–p structure of triple‐cation mixed‐halide [Cs0.05(MA0.17FA0.83)0.95Pb(I0.83Br0.17)3] bifacial perovskite solar cells with TiO2 and CuSbS2 as electron and hole transporting material respectively, is studied. The proposed device shows Voc 1.1761 V, Jsc 24.418 mA cm−2, fill factor (FF) 88.02%, and PCE 25.28% at front illumination and Voc 1.123 V, Jsc 3.609 mA cm−2, FF 84.75%, and PCE 17.19% at rear illumination.