Electromechanical properties of [0 0 1]‐textured Mn–PMN–PZT ceramics under uniaxial pressure

Dielectric, ferroelectric, and piezoelectric properties of both random and textured Mn–PMN–PZT ceramics were characterized under uniaxial stress. Textured ceramics exhibit a large piezoelectric response under uniaxial pressure; the bias field piezoelectric constant is higher than 700 pC/N when pressure is below 50 MPa. Moreover, textured ceramics also show better depolarization resistance under uniaxial stress fields; overall, 30% of the origin performance will remain when stress approaches 200 MPa, but for random ceramics, it is only 10%. The ferroelectricity of both random and textured ceramics is suppressed by uniaxial compression. Ec, Pr, Ei, and dissipation energy all decrease with increasing uniaxial stress. In addition, phase‐field simulation was used to better understand the polarization‐changing effects on piezoelectric and dielectric performance. The uniaxial stress causes polarization rotation and increases the angle between polarization and the electric field, which is an important factor leading to the increase of the dielectric constant.