Broadband near‐infrared (NIR) emitting Cr3+‐doped La3Ga5SnO14 phosphor with long persistent and photostimulated persistent luminescence

Recently, long persistent phosphors (LPPs) have attracted significant attention as promising candidates for biomedical applications. However, the serious decrease in luminescence intensity in tissue still remains a major challenge. Therefore, exploring more competitive LPPs and achieving reproducible tissue imaging is crucial. In this study, a new series of near‐infrared (NIR) phosphors La3Ga5Sn1‐xO14:xCr3+ (x = 0.005–0.05) were synthesized using a high‐temperature solid‐state method. The as‐synthesized samples were characterized using X‐ray diffraction, diffuse/photoluminescence spectroscopy, fluorescence decay curves, and thermoluminescence spectroscopy. Upon excitation with ultraviolet light, strong emission bands were observed in the range 600–1200 nm with an optimal doping concentration of x = 0.02 mol. Moreover, La3Ga5SnO14:Cr3+ exhibits persistent luminescence due to the presence of suitable energy traps, which prompted the phosphor to emit NIR light even after the removal of the excitation source. Upon excitation with UV/blue light, the sample exhibited strong emission bands in the range 600–1200 nm peaking at 937 nm. In addition, efficient infrared laser‐promoted photostimulated luminescence implies potential application in optical storage.