Ca-induced changes in the crystal structure and magnetic properties of barium hexaferrite

Ca-doped barium hexaferrite (Ba 1− x Ca x Fe 12 O 19; x = 0.1–0.6) samples were synthesized successfully using solid-state reaction route. Further, the limit of the Ca solubility in BaFe 12 O 19 has been investigated in the 900–1200°C temperature range. X-ray analysis reveals maximum Ca solubility in BFO at 1200°C (≈50%). The emergence of a hematite secondary phase at Ca concentrations ≈50 and 60 at% was observed. The XRD analysis also confirmed a gradual reduction in the c -parameter from 23.195 Å (at x = 0.1) to 23.147 Å (at x = 0.5). The structural data further suggested an enhancement of sample density with Ca substitution. Field-emission transmission electron microscopy micrographs reveal (a) distinct grain morphology at lower Ca concentration ( x = 0.1) and (b) enhanced secondary grain growth and grain amalgamation at higher Ca concentration ( x = 0.5). The M–H studies reveal that M r and M s almost stay constant up to x = 0.2, beyond which they start rising rapidly. M r ≈ 42.65 emu g −1 and M s ≈ 92.19 emu g −1 , exhibit a maximum at x = 0.4. The coercivity first decreases rapidly from 4168 Oe (at x = 0.0) to 2326 Oe (at x = 0.1) followed by a marginal decrease to 2045 Oe (at x = 0.4). An H c value ≥1200 Oe in a majority of our samples makes them potentially suitable for perpendicular recording media and permanent magnet applications.