Electrochemical hydrogen storage properties of melt-spun Ti0.9Zr0.1V0.2Ni1.5La0.5 alloy

The Ti0.9Zr0.1V0.2Ni1.5La0.5 alloy samples were synthesized by melt-spinning technique at the different wheel velocity (cooling rate), and the structure and electrochenfical hydrogen storage properties were investigated. The result indicated that the structure of the melt-spun ribbons mainly contain...

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Veröffentlicht in:Frontiers of Physics 2011-06, Vol.6 (2), p.209-213
Hauptverfasser: Wang, Jian, Che, Guang-bo, Wang, Qing-wei, Zhang, Wan-xi, Wang, Li-min
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Sprache:eng
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Zusammenfassung:The Ti0.9Zr0.1V0.2Ni1.5La0.5 alloy samples were synthesized by melt-spinning technique at the different wheel velocity (cooling rate), and the structure and electrochenfical hydrogen storage properties were investigated. The result indicated that the structure of the melt-spun ribbons mainly contains C14 Laves phase and V-based solid solution phase. The discharge capacity, cyclic stability, high-rate discharge ability and electrochemical kinetic of the alloy electrodes are correlated with the cooling rate (wheel velocity), and the maximum discharge capacity is over 200 mA.h/g at the wheel velocity of 20 m/s.
ISSN:2095-0462
2095-0470
1673-3606
DOI:10.1007/s11467-011-0177-0