Magnetic properties and magnetic entropy changes of MRE2Co7 compounds

(La0.5Ce0.5)2Co7 and(Ce0.65Pr0.35)2Co7 compounds for magnetic refrigeration were studied by X-ray diffraction, ac susceptibility and isothermal magnetization measurements. X-ray powder diffraction shows that all the compounds have hexagonal Ce2Ni7-type structure. The Curie temperatures(TC) are 258 K...

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Veröffentlicht in:Science China. Physics, mechanics & astronomy mechanics & astronomy, 2015-09, Vol.58 (9), p.86-89, Article 597501
Hauptverfasser: Zhong, XiChun, Liu, ZhongWu, Min, JiXiong, Tian, HuaCun, Gschneidner, Karl A., Pecharsky, Vitalij K.
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Sprache:eng
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Zusammenfassung:(La0.5Ce0.5)2Co7 and(Ce0.65Pr0.35)2Co7 compounds for magnetic refrigeration were studied by X-ray diffraction, ac susceptibility and isothermal magnetization measurements. X-ray powder diffraction shows that all the compounds have hexagonal Ce2Ni7-type structure. The Curie temperatures(TC) are 258 K and 222 K for(La0.5Ce0.5)2Co7 and(Ce0.65Pr0.35)2Co7 compounds, respectively. High coercivities(HC) of about 1.74 and 6.61 k Oe at 5 K with a smooth demagnetization curves were obtained for the(La0.5Ce0.5)2Co7 and(Ce0.65Pr0.35)2Co7 compounds, respectively. For an applied field change from 0 to 50 k Oe, the maximum(??SM) for(La0.5Ce0.5)2Co7 and(Ce0.65Pr0.35)2Co7 compounds are 0.52 and 0.67 J/(kg K), respectively.
ISSN:1674-7348
1869-1927
DOI:10.1007/s11433-015-5656-9