Linker extension through hard-soft selective metal coordination for the construction of a non-rigid metal-organic framework

A metal-organic framework （MOF） has been obtained by using a linker extension strategy. Three di-anions of 4-（3,5-dimethyl- 1H-pyrazol-4-yl）-benzoic acid coordinate to three Cu（I） ions forming an extended trigonal planar ligand, which links three di-copper paddlewheel units giving rise to a Pt304 ne...

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Veröffentlicht in:	Science China. Chemistry 2013-04, Vol.56 (4), p.418-422
Hauptverfasser:	Wei, ZhangWen, Yuan, DaQiang, Zhao, XiaoLiang, Sun, DaoFeng, Zhou, Hong-Cai
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzoic acid Chemistry Chemistry and Materials Science Chemistry/Food Science Communications Copper Metal-organic frameworks MOF 平面三角形连接器金属铜（I）阴离子非刚性骨架
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Beschreibung
Zusammenfassung:	A metal-organic framework （MOF） has been obtained by using a linker extension strategy. Three di-anions of 4-（3,5-dimethyl- 1H-pyrazol-4-yl）-benzoic acid coordinate to three Cu（I） ions forming an extended trigonal planar ligand, which links three di-copper paddlewheel units giving rise to a Pt304 net.
ISSN:	1674-7291 1869-1870
DOI:	10.1007/s11426-013-4851-7