One-Dimensional Supramolecular Hybrid Iodobismuthate (1-EtPy)3{[Bi2I9](I2)0.75}: Structural Features and Theoretical Studies of I···I Non-Covalent Interactions

One-Dimensional Supramolecular Hybrid Iodobismuthate (1-EtPy)3{[Bi2I9](I2)0.75}: Structural Features and Theoretical Studies of I···I Non-Covalent Interactions

In supramolecular complex (1-EtPy) 3 {[Bi 2 I 9 ](I 2 ) 0.75 } ( 1 ), diiodine fragments are “captured” by iodobismuthate anions via the system of non-covalent I···I interactions (halogen bonding). The energies of latter were estimated by theoretical methods; optical features and Raman spectrum are...

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Veröffentlicht in:Journal of cluster science 2021-05, Vol.32 (3), p.787-791
Hauptverfasser: Usoltsev, Andrey N., Korobeynikov, Nikita A., Novikov, Alexander S., Shayapov, Vladimir R., Korolkov, Ilya V., Samsonenko, Denis G., Fedin, Vladimir P., Sokolov, Maxim N., Adonin, Sergey A.
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemistry
Chemistry and Materials Science
Electrons
Inorganic Chemistry
Lasers
Ligands
Nanochemistry
Original Paper
Physical Chemistry
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Zusammenfassung:In supramolecular complex (1-EtPy) 3 {[Bi 2 I 9 ](I 2 ) 0.75 } ( 1 ), diiodine fragments are “captured” by iodobismuthate anions via the system of non-covalent I···I interactions (halogen bonding). The energies of latter were estimated by theoretical methods; optical features and Raman spectrum are discussed.
ISSN:1040-7278
1572-8862
DOI:10.1007/s10876-020-01843-2