The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogen...

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Veröffentlicht in:Journal of cluster science 2001-03, Vol.12 (1), p.139-173
Hauptverfasser: Brait, Sabrina, Deabate, Stefano, Knox, Selby A. R, Sappa, Enrico
Format: Artikel
Sprache:eng
Schlagworte:
Benzene
Carbonyls
Catalytic activity
Clusters
Transition metals
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Zusammenfassung:A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.
ISSN:1040-7278
1572-8862
DOI:10.1023/A:1016627113620