Electrochemistry of poly(5-phenyl dipyrromethane) and its characterization

In this work, electropolymerization of 5-phenyl dipyrromethane (DPM) and electrochemical behavior of the obtained polymer were performed. The monomer was electropolymerized in a solution of DPM and 0.1 M tetra- n -butyl ammonium perchlorate/dichloromethane supporting electrolyte/solvent solution sys...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2015-04, Vol.72 (4), p.867-879
Hauptverfasser: Bolat, Gulcin, Kuralay, Filiz, Temelli, Baris, Unaleroglu, Canan, Abaci, Serdar
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creator Bolat, Gulcin
Kuralay, Filiz
Temelli, Baris
Unaleroglu, Canan
Abaci, Serdar
description In this work, electropolymerization of 5-phenyl dipyrromethane (DPM) and electrochemical behavior of the obtained polymer were performed. The monomer was electropolymerized in a solution of DPM and 0.1 M tetra- n -butyl ammonium perchlorate/dichloromethane supporting electrolyte/solvent solution system on a Pt electrode by cyclic voltammetry technique. The polymeric film was then characterized by scanning electron microscopy, atomic force microscopy, fourier transform infrared-attenuated total reflectance, nuclear magnetic resonance spectroscopy, differential scanning calorimetry and alternative current impedance techniques.
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subjects Acids
Ammonium perchlorates
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complex Fluids and Microfluidics
Dichloromethane
Electrochemical analysis
Electrochemistry
Electrodes
Electrolytes
Fourier transforms
Microscopy
Morphology
NMR
NMR spectroscopy
Nuclear magnetic resonance
Organic Chemistry
Original Paper
Oxidation
Physical Chemistry
Polymer films
Polymer Sciences
Polymerization
Polymers
Scanning electron microscopy
Soft and Granular Matter
Spectrum analysis
Voltammetry
title Electrochemistry of poly(5-phenyl dipyrromethane) and its characterization
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