Cellulose-supported Pd nanoparticles: effective for the selective oxidation of glucose into gluconic acid
Cellulose-supported on Pd nanoparticles (Pd/cellulose) were successfully prepared by chemical reduction technique and characterized by various experimental tools. The Pd/cellulose catalyst was found to effectively promote the oxidation of glucose into gluconic acid under mild conditions. The base pl...
Gespeichert in:
| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2020-02, Vol.77 (2), p.1003-1014 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1014 |
|---|---|
| container_issue | 2 |
| container_start_page | 1003 |
| container_title | Polymer bulletin (Berlin, Germany) |
| container_volume | 77 |
| creator | Zhang, Xinxin Shi, Haoyan Chi, Quan Liu, Xixi Chen, Lianqing |
| description | Cellulose-supported on Pd nanoparticles (Pd/cellulose) were successfully prepared by chemical reduction technique and characterized by various experimental tools. The Pd/cellulose catalyst was found to effectively promote the oxidation of glucose into gluconic acid under mild conditions. The base played a crucial role in the oxidation of glucose into gluconic acid. Glucose was fully converted at room temperature after 3 h by the use of stoichiometric amount of Na
2
CO
3
to neutralize gluconic acid, and gluconic acid was obtained in a high yield of 91.2%. The catalyst was recovered from product and reused up to five times without significant loss in its catalytic activity. |
| doi_str_mv | 10.1007/s00289-019-02749-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2918060346</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2918060346</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-acb152f8dd0fb7dafd0223a05beecb96f2e63afa6c2f465c67df9da9499265023</originalsourceid><addsrcrecordid>eNp9kEtLxDAUhYMoOI7-AVcB19WbR9OJOxl8wYAudB3SPMYMtalJK_rvjVZw5-JyOZdzzoUPoVMC5wSgucgAdCUrIGVow2XF99CCcCYqyrncRwsgDVSwYvIQHeW8g6KFIAsU1q7rpi5mV-VpGGIancWPFve6j4NOYzCdy5fYee_MGN4d9jHh8cXh7LrfS_wIVo8h9jh6vO0mU8pw6Mc4iz4YrE2wx-jA6y67k9-9RM8310_ru2rzcHu_vtpUhtVirLRpSU39ylrwbWO1t0Ap01C3zplWCk-dYNprYajnojaisV5aLbmUVNRA2RKdzb1Dim-Ty6PaxSn15aWikqxAAOOiuOjsMinmnJxXQwqvOn0qAuobqZqRqoJU_SBVvITYHMrF3G9d-qv-J_UFdBR8EA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2918060346</pqid></control><display><type>article</type><title>Cellulose-supported Pd nanoparticles: effective for the selective oxidation of glucose into gluconic acid</title><source>Springer Online Journals Complete</source><source>ProQuest Central UK/Ireland</source><source>ProQuest Central</source><creator>Zhang, Xinxin ; Shi, Haoyan ; Chi, Quan ; Liu, Xixi ; Chen, Lianqing</creator><creatorcontrib>Zhang, Xinxin ; Shi, Haoyan ; Chi, Quan ; Liu, Xixi ; Chen, Lianqing</creatorcontrib><description>Cellulose-supported on Pd nanoparticles (Pd/cellulose) were successfully prepared by chemical reduction technique and characterized by various experimental tools. The Pd/cellulose catalyst was found to effectively promote the oxidation of glucose into gluconic acid under mild conditions. The base played a crucial role in the oxidation of glucose into gluconic acid. Glucose was fully converted at room temperature after 3 h by the use of stoichiometric amount of Na
2
CO
3
to neutralize gluconic acid, and gluconic acid was obtained in a high yield of 91.2%. The catalyst was recovered from product and reused up to five times without significant loss in its catalytic activity.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-019-02749-4</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Catalysts ; Catalytic activity ; Catalytic oxidation ; Cellulose ; Characterization and Evaluation of Materials ; Chemical reduction ; Chemicals ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Cotton ; Gluconic acid ; Glucose ; Metal oxides ; Nanoparticles ; Organic Chemistry ; Original Paper ; Oxidation ; Palladium ; Physical Chemistry ; Polymer Sciences ; Polymers ; Room temperature ; Soft and Granular Matter</subject><ispartof>Polymer bulletin (Berlin, Germany), 2020-02, Vol.77 (2), p.1003-1014</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-acb152f8dd0fb7dafd0223a05beecb96f2e63afa6c2f465c67df9da9499265023</citedby><cites>FETCH-LOGICAL-c356t-acb152f8dd0fb7dafd0223a05beecb96f2e63afa6c2f465c67df9da9499265023</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-019-02749-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918060346?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,41488,42557,43805,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Zhang, Xinxin</creatorcontrib><creatorcontrib>Shi, Haoyan</creatorcontrib><creatorcontrib>Chi, Quan</creatorcontrib><creatorcontrib>Liu, Xixi</creatorcontrib><creatorcontrib>Chen, Lianqing</creatorcontrib><title>Cellulose-supported Pd nanoparticles: effective for the selective oxidation of glucose into gluconic acid</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>Cellulose-supported on Pd nanoparticles (Pd/cellulose) were successfully prepared by chemical reduction technique and characterized by various experimental tools. The Pd/cellulose catalyst was found to effectively promote the oxidation of glucose into gluconic acid under mild conditions. The base played a crucial role in the oxidation of glucose into gluconic acid. Glucose was fully converted at room temperature after 3 h by the use of stoichiometric amount of Na
2
CO
3
to neutralize gluconic acid, and gluconic acid was obtained in a high yield of 91.2%. The catalyst was recovered from product and reused up to five times without significant loss in its catalytic activity.</description><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Catalytic oxidation</subject><subject>Cellulose</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical reduction</subject><subject>Chemicals</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Cotton</subject><subject>Gluconic acid</subject><subject>Glucose</subject><subject>Metal oxides</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Palladium</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Room temperature</subject><subject>Soft and Granular Matter</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kEtLxDAUhYMoOI7-AVcB19WbR9OJOxl8wYAudB3SPMYMtalJK_rvjVZw5-JyOZdzzoUPoVMC5wSgucgAdCUrIGVow2XF99CCcCYqyrncRwsgDVSwYvIQHeW8g6KFIAsU1q7rpi5mV-VpGGIancWPFve6j4NOYzCdy5fYee_MGN4d9jHh8cXh7LrfS_wIVo8h9jh6vO0mU8pw6Mc4iz4YrE2wx-jA6y67k9-9RM8310_ru2rzcHu_vtpUhtVirLRpSU39ylrwbWO1t0Ap01C3zplWCk-dYNprYajnojaisV5aLbmUVNRA2RKdzb1Dim-Ty6PaxSn15aWikqxAAOOiuOjsMinmnJxXQwqvOn0qAuobqZqRqoJU_SBVvITYHMrF3G9d-qv-J_UFdBR8EA</recordid><startdate>20200201</startdate><enddate>20200201</enddate><creator>Zhang, Xinxin</creator><creator>Shi, Haoyan</creator><creator>Chi, Quan</creator><creator>Liu, Xixi</creator><creator>Chen, Lianqing</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20200201</creationdate><title>Cellulose-supported Pd nanoparticles: effective for the selective oxidation of glucose into gluconic acid</title><author>Zhang, Xinxin ; Shi, Haoyan ; Chi, Quan ; Liu, Xixi ; Chen, Lianqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-acb152f8dd0fb7dafd0223a05beecb96f2e63afa6c2f465c67df9da9499265023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Catalytic oxidation</topic><topic>Cellulose</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical reduction</topic><topic>Chemicals</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Cotton</topic><topic>Gluconic acid</topic><topic>Glucose</topic><topic>Metal oxides</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Palladium</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Room temperature</topic><topic>Soft and Granular Matter</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xinxin</creatorcontrib><creatorcontrib>Shi, Haoyan</creatorcontrib><creatorcontrib>Chi, Quan</creatorcontrib><creatorcontrib>Liu, Xixi</creatorcontrib><creatorcontrib>Chen, Lianqing</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xinxin</au><au>Shi, Haoyan</au><au>Chi, Quan</au><au>Liu, Xixi</au><au>Chen, Lianqing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cellulose-supported Pd nanoparticles: effective for the selective oxidation of glucose into gluconic acid</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2020-02-01</date><risdate>2020</risdate><volume>77</volume><issue>2</issue><spage>1003</spage><epage>1014</epage><pages>1003-1014</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>Cellulose-supported on Pd nanoparticles (Pd/cellulose) were successfully prepared by chemical reduction technique and characterized by various experimental tools. The Pd/cellulose catalyst was found to effectively promote the oxidation of glucose into gluconic acid under mild conditions. The base played a crucial role in the oxidation of glucose into gluconic acid. Glucose was fully converted at room temperature after 3 h by the use of stoichiometric amount of Na
2
CO
3
to neutralize gluconic acid, and gluconic acid was obtained in a high yield of 91.2%. The catalyst was recovered from product and reused up to five times without significant loss in its catalytic activity.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-019-02749-4</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2020-02, Vol.77 (2), p.1003-1014 |
| issn | 0170-0839 1436-2449 |
| language | eng |
| recordid | cdi_proquest_journals_2918060346 |
| source | Springer Online Journals Complete; ProQuest Central UK/Ireland; ProQuest Central |
| subjects | Catalysts Catalytic activity Catalytic oxidation Cellulose Characterization and Evaluation of Materials Chemical reduction Chemicals Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Cotton Gluconic acid Glucose Metal oxides Nanoparticles Organic Chemistry Original Paper Oxidation Palladium Physical Chemistry Polymer Sciences Polymers Room temperature Soft and Granular Matter |
| title | Cellulose-supported Pd nanoparticles: effective for the selective oxidation of glucose into gluconic acid |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T16%3A27%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Cellulose-supported%20Pd%20nanoparticles:%20effective%20for%20the%20selective%20oxidation%20of%20glucose%20into%20gluconic%20acid&rft.jtitle=Polymer%20bulletin%20(Berlin,%20Germany)&rft.au=Zhang,%20Xinxin&rft.date=2020-02-01&rft.volume=77&rft.issue=2&rft.spage=1003&rft.epage=1014&rft.pages=1003-1014&rft.issn=0170-0839&rft.eissn=1436-2449&rft_id=info:doi/10.1007/s00289-019-02749-4&rft_dat=%3Cproquest_cross%3E2918060346%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2918060346&rft_id=info:pmid/&rfr_iscdi=true |