Cellulose-supported Pd nanoparticles: effective for the selective oxidation of glucose into gluconic acid

Cellulose-supported on Pd nanoparticles (Pd/cellulose) were successfully prepared by chemical reduction technique and characterized by various experimental tools. The Pd/cellulose catalyst was found to effectively promote the oxidation of glucose into gluconic acid under mild conditions. The base pl...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2020-02, Vol.77 (2), p.1003-1014
Hauptverfasser: Zhang, Xinxin, Shi, Haoyan, Chi, Quan, Liu, Xixi, Chen, Lianqing
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Sprache:eng
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Zusammenfassung:Cellulose-supported on Pd nanoparticles (Pd/cellulose) were successfully prepared by chemical reduction technique and characterized by various experimental tools. The Pd/cellulose catalyst was found to effectively promote the oxidation of glucose into gluconic acid under mild conditions. The base played a crucial role in the oxidation of glucose into gluconic acid. Glucose was fully converted at room temperature after 3 h by the use of stoichiometric amount of Na 2 CO 3 to neutralize gluconic acid, and gluconic acid was obtained in a high yield of 91.2%. The catalyst was recovered from product and reused up to five times without significant loss in its catalytic activity.
ISSN:0170-0839
1436-2449
DOI:10.1007/s00289-019-02749-4