KA2 and A3 coupling reactions promoted by Fe3O4@T-CS@Cys@Ag+ nanocomposite

Chitosan biopolymer was functionalized with cysteine amino acid via trichloro-1,3,5-triazine-bridged agent. The magnetization process was done due to the treatment of functionalized chitosan with iron oxide nanoparticles. In the final nanocomposite (Fe 3 O 4 @T-CS@Cys@Ag + ), thiol and carboxylate g...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2022-05, Vol.79 (5), p.2799-2817
Hauptverfasser: Rafiee, F., Hosseinvand, S.
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description Chitosan biopolymer was functionalized with cysteine amino acid via trichloro-1,3,5-triazine-bridged agent. The magnetization process was done due to the treatment of functionalized chitosan with iron oxide nanoparticles. In the final nanocomposite (Fe 3 O 4 @T-CS@Cys@Ag + ), thiol and carboxylate groups of cysteine were surrounded by silver ions. The catalytic activity of the prepared nanocomposite was studied in KA 2 and A 3 coupling reactions for the synthesis of propargylamines.
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subjects Amino acids
Biopolymers
Catalytic activity
Characterization and Evaluation of Materials
Chemical reactions
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chitosan
Complex Fluids and Microfluidics
Coupling
Cysteine
Ethanol
Fourier transforms
Iron oxides
Morphology
Nanocomposites
Nanoparticles
Organic Chemistry
Original Paper
Physical Chemistry
Polymer Sciences
Scanning electron microscopy
Scientific imaging
Silver
Soft and Granular Matter
title KA2 and A3 coupling reactions promoted by Fe3O4@T-CS@Cys@Ag+ nanocomposite
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