A Simple, Accurate Method to Determine the Effective Value of the Magnetic Induction of the Microwave Field from the Continuous Saturation of EPR Spectra of Fremy’s Salt Solutions. Representative values of T1
A simple protocol to measure the effective value of the circularly polarized magnetic induction of the microwave field is proposed and demonstrated employing continuous-wave saturation of a standard sample of Fremy’s salt measured under specified conditions. The fact that the doubly integrated inten...
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| Veröffentlicht in: | Applied magnetic resonance 2019-07, Vol.50 (7), p.919-942 |
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| container_end_page | 942 |
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| container_title | Applied magnetic resonance |
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| creator | Bakirov, M. M. Salikhov, K. M. Peric, Miroslav Schwartz, Robert N. Bales, Barney L. |
| description | A simple protocol to measure the effective value of the circularly polarized magnetic induction of the microwave field is proposed and demonstrated employing continuous-wave saturation of a standard sample of Fremy’s salt measured under specified conditions. The fact that the doubly integrated intensity of first-derivative spectra is invariant with respect to the line shape is used to take into account the non-Lorentzian line shape to study the peak-to-peak intensity or the line width. Corrections for the use of line- rather than point-samples are developed. |
| doi_str_mv | 10.1007/s00723-019-01120-0 |
| format | Article |
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| subjects | Atoms and Molecules in Strong Fields Circular polarization Continuous radiation Laser Matter Interaction Line shape Magnetic induction Organic Chemistry Original Paper Physical Chemistry Physics Physics and Astronomy Saline solutions Solid State Physics Spectra Spectroscopy/Spectrometry |
| title | A Simple, Accurate Method to Determine the Effective Value of the Magnetic Induction of the Microwave Field from the Continuous Saturation of EPR Spectra of Fremy’s Salt Solutions. Representative values of T1 |
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