A Simple, Accurate Method to Determine the Effective Value of the Magnetic Induction of the Microwave Field from the Continuous Saturation of EPR Spectra of Fremy’s Salt Solutions. Representative values of T1

A simple protocol to measure the effective value of the circularly polarized magnetic induction of the microwave field is proposed and demonstrated employing continuous-wave saturation of a standard sample of Fremy’s salt measured under specified conditions. The fact that the doubly integrated inten...

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Veröffentlicht in:Applied magnetic resonance 2019-07, Vol.50 (7), p.919-942
Hauptverfasser: Bakirov, M. M., Salikhov, K. M., Peric, Miroslav, Schwartz, Robert N., Bales, Barney L.
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Sprache:eng
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Zusammenfassung:A simple protocol to measure the effective value of the circularly polarized magnetic induction of the microwave field is proposed and demonstrated employing continuous-wave saturation of a standard sample of Fremy’s salt measured under specified conditions. The fact that the doubly integrated intensity of first-derivative spectra is invariant with respect to the line shape is used to take into account the non-Lorentzian line shape to study the peak-to-peak intensity or the line width. Corrections for the use of line- rather than point-samples are developed.
ISSN:0937-9347
1613-7507
DOI:10.1007/s00723-019-01120-0