A Simple, Accurate Method to Determine the Effective Value of the Magnetic Induction of the Microwave Field from the Continuous Saturation of EPR Spectra of Fremy’s Salt Solutions. Representative values of T1
A simple protocol to measure the effective value of the circularly polarized magnetic induction of the microwave field is proposed and demonstrated employing continuous-wave saturation of a standard sample of Fremy’s salt measured under specified conditions. The fact that the doubly integrated inten...
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Veröffentlicht in: | Applied magnetic resonance 2019-07, Vol.50 (7), p.919-942 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A simple protocol to measure the effective value of the circularly polarized magnetic induction of the microwave field is proposed and demonstrated employing continuous-wave saturation of a standard sample of Fremy’s salt measured under specified conditions. The fact that the doubly integrated intensity of first-derivative spectra is invariant with respect to the line shape is used to take into account the non-Lorentzian line shape to study the peak-to-peak intensity or the line width. Corrections for the use of line- rather than point-samples are developed. |
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ISSN: | 0937-9347 1613-7507 |
DOI: | 10.1007/s00723-019-01120-0 |