Synthesis of vinyloxy phosphorus monomers from the enolate of acetaldehyde

Synthesis of vinyloxy phosphorus monomers from the enolate of acetaldehyde

SummaryA simple synthetic procedure for vinyloxy phosphorus monomers involves the reaction of the enolate of acetaldehyde, obtained from the cycloreversion of tetrahydrofuran in the presence of n-butyllithium, with chlorophosphites or phosphorochloridates leading to vinyl phosphites or vinyl phospha...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2000-12, Vol.45 (4-5), p.359-364
Hauptverfasser: JOHNSTON, K. F, PADIAS, Anne Buyle, HALL, H. K
Format: Artikel
Sprache:eng
Schlagworte:
Acetaldehyde
Applied sciences
Butyllithium
Exact sciences and technology
Inorganic salts
Model compounds
Monomers
Organic polymers
Phosphates
Phosphorus
Physicochemistry of polymers
Tetrahydrofuran
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Zusammenfassung:SummaryA simple synthetic procedure for vinyloxy phosphorus monomers involves the reaction of the enolate of acetaldehyde, obtained from the cycloreversion of tetrahydrofuran in the presence of n-butyllithium, with chlorophosphites or phosphorochloridates leading to vinyl phosphites or vinyl phosphates, respectively, in high yield and purity.
ISSN:0170-0839
1436-2449
DOI:10.1007/s002890070008