Effect of strain rate on the behavior of three-dimensional polymers of oligoesteracrylates under the conditions of the uniaxial elongation
For three-dimensional polymers based on the dimethacryloil derivatives adipic and sebasinoil acids and dicarbonyloxyethylene we have established the influence of the deformation velocity ( V ε ) on their behaviour under the conditions of the uniaxial elongation. With the increase of V ε up to a dist...
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Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2011-08, Vol.67 (4), p.641-652 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | For three-dimensional polymers based on the dimethacryloil derivatives adipic and sebasinoil acids and dicarbonyloxyethylene we have established the influence of the deformation velocity (
V
ε
) on their behaviour under the conditions of the uniaxial elongation. With the increase of
V
ε
up to a distinct value of
V
ε
l
, the ultimate stress
σ
m
for of the polymers grows, but at
V
ε
>
V
εl
the value of
σ
m
decreases. This phenomenon is explained. With the rise of
V
ε
, the module of elasticity
E
1
increases and the curves σ(ε) are shifted to the left along the ε axis. The change of the character of the structural organization of three-dimensional polymers in the deformation process of their samples was established. |
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ISSN: | 0170-0839 1436-2449 |
DOI: | 10.1007/s00289-010-0430-7 |