Effect of strain rate on the behavior of three-dimensional polymers of oligoesteracrylates under the conditions of the uniaxial elongation

For three-dimensional polymers based on the dimethacryloil derivatives adipic and sebasinoil acids and dicarbonyloxyethylene we have established the influence of the deformation velocity ( V ε ) on their behaviour under the conditions of the uniaxial elongation. With the increase of V ε up to a dist...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2011-08, Vol.67 (4), p.641-652
Hauptverfasser: Kireeva, S. M., Sivergin, Yu. M.
Format: Artikel
Sprache:eng
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Zusammenfassung:For three-dimensional polymers based on the dimethacryloil derivatives adipic and sebasinoil acids and dicarbonyloxyethylene we have established the influence of the deformation velocity ( V ε ) on their behaviour under the conditions of the uniaxial elongation. With the increase of V ε up to a distinct value of V ε l , the ultimate stress σ m for of the polymers grows, but at V ε  >  V εl the value of σ m decreases. This phenomenon is explained. With the rise of V ε , the module of elasticity E 1 increases and the curves σ(ε) are shifted to the left along the ε axis. The change of the character of the structural organization of three-dimensional polymers in the deformation process of their samples was established.
ISSN:0170-0839
1436-2449
DOI:10.1007/s00289-010-0430-7