TEMPO-oxidized cellulose nanofibers/TiO2 nanocomposite as new adsorbent for Brilliant Blue dye removal
In this article, TEMPO-oxidized cellulose nanofiber (TEMPO-CNF) prepared from bagasse was described and utilized as a sustainable material for the preparation of new nanocomposites. TiO 2 nanoparticles were synthesized by in situ precipitation in the presence of TEMPO-CNF. The prepared nanocomposite...
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Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2020-12, Vol.77 (12), p.6213-6226 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In this article, TEMPO-oxidized cellulose nanofiber (TEMPO-CNF) prepared from bagasse was described and utilized as a sustainable material for the preparation of new nanocomposites. TiO
2
nanoparticles were synthesized by in situ precipitation in the presence of TEMPO-CNF. The prepared nanocomposite, TEMPO-CNF/TiO
2
, was characterized by using FT-IR, XRD, TGA, SEM, and EDX analysis. The results proved that homogenous spherical TiO
2
nanoparticles were formed with the particles of TEMPO-CNF. TEMPO-CNF/TiO
2
nanocomposite was examined as an adsorbent for Brilliant Blue (BB) adsorption. The highest BB removal efficiency was observed at pH 7, the adsorption process is well described by pseudo-second-order and Langmuir adsorption model, and the maximum adsorption capacity is 162 mg/g. Our results proved that the TEMPO-CNF/TiO
2
nanocomposite could be used for the removal of BB from aqueous solutions. |
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ISSN: | 0170-0839 1436-2449 |
DOI: | 10.1007/s00289-019-03068-4 |