TEMPO-oxidized cellulose nanofibers/TiO2 nanocomposite as new adsorbent for Brilliant Blue dye removal

In this article, TEMPO-oxidized cellulose nanofiber (TEMPO-CNF) prepared from bagasse was described and utilized as a sustainable material for the preparation of new nanocomposites. TiO 2 nanoparticles were synthesized by in situ precipitation in the presence of TEMPO-CNF. The prepared nanocomposite...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2020-12, Vol.77 (12), p.6213-6226
Hauptverfasser: Al-Ahmed, Zehbah Ali, Hassan, Abeer A., El-Khouly, Sahar M., El-Shafey, Shaymaa E.
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Sprache:eng
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Zusammenfassung:In this article, TEMPO-oxidized cellulose nanofiber (TEMPO-CNF) prepared from bagasse was described and utilized as a sustainable material for the preparation of new nanocomposites. TiO 2 nanoparticles were synthesized by in situ precipitation in the presence of TEMPO-CNF. The prepared nanocomposite, TEMPO-CNF/TiO 2 , was characterized by using FT-IR, XRD, TGA, SEM, and EDX analysis. The results proved that homogenous spherical TiO 2 nanoparticles were formed with the particles of TEMPO-CNF. TEMPO-CNF/TiO 2 nanocomposite was examined as an adsorbent for Brilliant Blue (BB) adsorption. The highest BB removal efficiency was observed at pH 7, the adsorption process is well described by pseudo-second-order and Langmuir adsorption model, and the maximum adsorption capacity is 162 mg/g. Our results proved that the TEMPO-CNF/TiO 2 nanocomposite could be used for the removal of BB from aqueous solutions.
ISSN:0170-0839
1436-2449
DOI:10.1007/s00289-019-03068-4