A new azo initiator for the synthesis of polymers with pyrene terminal groups
Summary4,4′-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4′-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP...
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Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2004-06, Vol.52 (1), p.17-23 |
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creator | HEPUZER, Yesim GUVENER, Ufuk YAGCI, Yusuf |
description | Summary4,4′-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4′-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP) and stable free radical polymerization (SFRP) techniques. Incorporatioil of terminal groups were confirmed by spectral measurements. |
doi_str_mv | 10.1007/s00289-004-0244-6 |
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ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP) and stable free radical polymerization (SFRP) techniques. Incorporatioil of terminal groups were confirmed by spectral measurements.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-004-0244-6</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Applied sciences ; Chemical synthesis ; Exact sciences and technology ; Free radical polymerization ; Free radicals ; Physicochemistry of polymers ; Polystyrene resins</subject><ispartof>Polymer bulletin (Berlin, Germany), 2004-06, Vol.52 (1), p.17-23</ispartof><rights>2005 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2004.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c301t-77716a250114aa61fffd9a2aeb565f169a07282877dbe8d9441739624d73b63f3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2917871302?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,43805,64385,64389,72469</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15869968$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>HEPUZER, Yesim</creatorcontrib><creatorcontrib>GUVENER, Ufuk</creatorcontrib><creatorcontrib>YAGCI, Yusuf</creatorcontrib><title>A new azo initiator for the synthesis of polymers with pyrene terminal groups</title><title>Polymer bulletin (Berlin, Germany)</title><description>Summary4,4′-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4′-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP) and stable free radical polymerization (SFRP) techniques. Incorporatioil of terminal groups were confirmed by spectral measurements.</description><subject>Applied sciences</subject><subject>Chemical synthesis</subject><subject>Exact sciences and technology</subject><subject>Free radical polymerization</subject><subject>Free radicals</subject><subject>Physicochemistry of polymers</subject><subject>Polystyrene resins</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpFkEtLAzEUhYMoWKs_wF1AXEZvHpNMlqX4goobXYd0JrEp08mYTCn115vSgovL4cA5h8uH0C2FBwqgHjMAqzUBEASYEESeoQkVXJJi9DmaAFVAoOb6El3lvIbipaQT9D7Dvdth-xtx6MMY7BgT9uXGlcN53xfJIePo8RC7_caljHdhXOFhn1zv8OjSJvS2w98pbod8jS687bK7OekUfT0_fc5fyeLj5W0-W5CGAx2JUopKyyqgVFgrqfe-1ZZZt6xk5anUFhSrWa1Uu3R1q4WgimvJRKv4UnLPp-juuDuk-LN1eTTruE3lj2yYpqpWlAMrKXpMNSnmnJw3Qwobm_aGgjlQM0dqplAzB2pGls79adnmxnY-2b4J-b9Y1VJrWfM_g3Br3w</recordid><startdate>20040601</startdate><enddate>20040601</enddate><creator>HEPUZER, Yesim</creator><creator>GUVENER, Ufuk</creator><creator>YAGCI, Yusuf</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20040601</creationdate><title>A new azo initiator for the synthesis of polymers with pyrene terminal groups</title><author>HEPUZER, Yesim ; GUVENER, Ufuk ; YAGCI, Yusuf</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c301t-77716a250114aa61fffd9a2aeb565f169a07282877dbe8d9441739624d73b63f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Chemical synthesis</topic><topic>Exact sciences and technology</topic><topic>Free radical polymerization</topic><topic>Free radicals</topic><topic>Physicochemistry of polymers</topic><topic>Polystyrene resins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>HEPUZER, Yesim</creatorcontrib><creatorcontrib>GUVENER, Ufuk</creatorcontrib><creatorcontrib>YAGCI, Yusuf</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HEPUZER, Yesim</au><au>GUVENER, Ufuk</au><au>YAGCI, Yusuf</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new azo initiator for the synthesis of polymers with pyrene terminal groups</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>2004-06-01</date><risdate>2004</risdate><volume>52</volume><issue>1</issue><spage>17</spage><epage>23</epage><pages>17-23</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>Summary4,4′-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4′-azobis(4-cyanopentanoyl chloride) (ACPC). 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subjects | Applied sciences Chemical synthesis Exact sciences and technology Free radical polymerization Free radicals Physicochemistry of polymers Polystyrene resins |
title | A new azo initiator for the synthesis of polymers with pyrene terminal groups |
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