A new azo initiator for the synthesis of polymers with pyrene terminal groups

Summary4,4′-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4′-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2004-06, Vol.52 (1), p.17-23
Hauptverfasser: HEPUZER, Yesim, GUVENER, Ufuk, YAGCI, Yusuf
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GUVENER, Ufuk
YAGCI, Yusuf
description Summary4,4′-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4′-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP) and stable free radical polymerization (SFRP) techniques. Incorporatioil of terminal groups were confirmed by spectral measurements.
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subjects Applied sciences
Chemical synthesis
Exact sciences and technology
Free radical polymerization
Free radicals
Physicochemistry of polymers
Polystyrene resins
title A new azo initiator for the synthesis of polymers with pyrene terminal groups
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