A new azo initiator for the synthesis of polymers with pyrene terminal groups

A new azo initiator for the synthesis of polymers with pyrene terminal groups

Summary4,4′-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4′-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2004-06, Vol.52 (1), p.17-23
Hauptverfasser: HEPUZER, Yesim, GUVENER, Ufuk, YAGCI, Yusuf
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Chemical synthesis
Exact sciences and technology
Free radical polymerization
Free radicals
Physicochemistry of polymers
Polystyrene resins
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Zusammenfassung:Summary4,4′-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4′-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP) and stable free radical polymerization (SFRP) techniques. Incorporatioil of terminal groups were confirmed by spectral measurements.
ISSN:0170-0839
1436-2449
DOI:10.1007/s00289-004-0244-6