Synthesis of heterobifunctional poly(ethy1ene glycol)containing an acryloyl group at one end and anisocyanate group at the other end
SummaryA New heterobifunctional poly(ethylene glycol) (PEG) having a polymerizable acryloyl group at one end and an isocyanate group at the other end was prepared in three efficient steps from commercially available t–Boc–PEG–NH2. The end groups were characterized by 1H NMR and MALDI–TOF–MS spectros...
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Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2004-08, Vol.52 (2), p.109-115 |
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creator | Won, Chee-Youb |
description | SummaryA New heterobifunctional poly(ethylene glycol) (PEG) having a polymerizable acryloyl group at one end and an isocyanate group at the other end was prepared in three efficient steps from commercially available t–Boc–PEG–NH2. The end groups were characterized by 1H NMR and MALDI–TOF–MS spectroscopy. Conjugation of the resulting PEG onto dextran via stable urethane linkage gave the PEG graft polymer with an acryloyl group at the free end of the graft chain. |
doi_str_mv | 10.1007/s00289-004-0264-2 |
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The end groups were characterized by 1H NMR and MALDI–TOF–MS spectroscopy. Conjugation of the resulting PEG onto dextran via stable urethane linkage gave the PEG graft polymer with an acryloyl group at the free end of the graft chain.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-004-0264-2</identifier><language>eng</language><publisher>Heidelberg: Springer Nature B.V</publisher><subject>Conjugation ; Dextrans ; Isocyanates ; NMR ; Nuclear magnetic resonance ; Polyethylene glycol</subject><ispartof>Polymer bulletin (Berlin, Germany), 2004-08, Vol.52 (2), p.109-115</ispartof><rights>Springer-Verlag Berlin Heidelberg 2004.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2917867640?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,43781</link.rule.ids></links><search><creatorcontrib>Won, Chee-Youb</creatorcontrib><title>Synthesis of heterobifunctional poly(ethy1ene glycol)containing an acryloyl group at one end and anisocyanate group at the other end</title><title>Polymer bulletin (Berlin, Germany)</title><description>SummaryA New heterobifunctional poly(ethylene glycol) (PEG) having a polymerizable acryloyl group at one end and an isocyanate group at the other end was prepared in three efficient steps from commercially available t–Boc–PEG–NH2. The end groups were characterized by 1H NMR and MALDI–TOF–MS spectroscopy. Conjugation of the resulting PEG onto dextran via stable urethane linkage gave the PEG graft polymer with an acryloyl group at the free end of the graft chain.</description><subject>Conjugation</subject><subject>Dextrans</subject><subject>Isocyanates</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Polyethylene glycol</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqNjk9LxDAQxYMoWP98AG8BL3qIO2lD2p5F8a73JRvTNkuYqUl6yN0PbhYErx7eGx7vB_MYu5PwJAH6XQJoh1EAKAGtVqI9Y41UnRatUuM5a0D2IGDoxkt2ldIRatZaNuz7vWBeXPKJ08QXl12kg582tNkTmsBXCuXB5aVIh47PoVgKj5YwG48eZ26QGxtLoBL4HGlbucmcKurws5Yn-US2GDTZ_RH1J6dq8cTdsIvJhORuf-81u399-Xh-E2ukr82lvD_SFuuatG9H2Q-61wq6_1E_JdpZlA</recordid><startdate>20040801</startdate><enddate>20040801</enddate><creator>Won, Chee-Youb</creator><general>Springer Nature B.V</general><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20040801</creationdate><title>Synthesis of heterobifunctional poly(ethy1ene glycol)containing an acryloyl group at one end and anisocyanate group at the other end</title><author>Won, Chee-Youb</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_journals_29178676403</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Conjugation</topic><topic>Dextrans</topic><topic>Isocyanates</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Polyethylene glycol</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Won, Chee-Youb</creatorcontrib><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Won, Chee-Youb</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of heterobifunctional poly(ethy1ene glycol)containing an acryloyl group at one end and anisocyanate group at the other end</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>2004-08-01</date><risdate>2004</risdate><volume>52</volume><issue>2</issue><spage>109</spage><epage>115</epage><pages>109-115</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>SummaryA New heterobifunctional poly(ethylene glycol) (PEG) having a polymerizable acryloyl group at one end and an isocyanate group at the other end was prepared in three efficient steps from commercially available t–Boc–PEG–NH2. The end groups were characterized by 1H NMR and MALDI–TOF–MS spectroscopy. Conjugation of the resulting PEG onto dextran via stable urethane linkage gave the PEG graft polymer with an acryloyl group at the free end of the graft chain.</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/s00289-004-0264-2</doi></addata></record> |
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source | SpringerLink Journals - AutoHoldings; ProQuest Central |
subjects | Conjugation Dextrans Isocyanates NMR Nuclear magnetic resonance Polyethylene glycol |
title | Synthesis of heterobifunctional poly(ethy1ene glycol)containing an acryloyl group at one end and anisocyanate group at the other end |
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