On the pseudoharmonic oscillator as a model for the electronic potential-energy function of a diatomic molecule
We show that the vibration-rotational energies of some diatomic molecules obtained some time ago are incorrect. The authors resorted to the experimental dissociation energy to construct the electronic potential-energy function by means of the pseudoharmonic potential that does not allow dissociation...
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Veröffentlicht in: | Journal of mathematical chemistry 2024-02, Vol.62 (2), p.313-316 |
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Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | We show that the vibration-rotational energies of some diatomic molecules obtained some time ago are incorrect. The authors resorted to the experimental dissociation energy to construct the electronic potential-energy function by means of the pseudoharmonic potential that does not allow dissociation. Besides, the restriction of the angular momentum quantum number exhibited by their results is incorrect from mathematical and physical points of views. |
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ISSN: | 0259-9791 1572-8897 |
DOI: | 10.1007/s10910-023-01530-3 |