Pd-catalyzed vinyl C–H amination with diaziridinone

Pd-catalyzed vinyl C–H amination with diaziridinone

This work describes a Pd-catalyzed vinyl C–H amination of N -(quinolin-8-yl)acrylamides with di- t -butyldiaziridinone, providing ready access to a variety of 3-amino- N -(quinolin-8-yl)acrylamides. The reaction likely proceeds via vinyl C–H activation to form a pallada( ii )cycle and subsequent ami...

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Veröffentlicht in:Organic Chemistry Frontiers 2024-01, Vol.11 (2), p.484-488
Hauptverfasser: Wang, Jianjun, Hong, Huiying, Hu, Daguo, Liu, Jieling, Liu, Wei, Shi, Yian
Format: Artikel
Sprache:eng
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Organic chemistry
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Zusammenfassung:This work describes a Pd-catalyzed vinyl C–H amination of N -(quinolin-8-yl)acrylamides with di- t -butyldiaziridinone, providing ready access to a variety of 3-amino- N -(quinolin-8-yl)acrylamides. The reaction likely proceeds via vinyl C–H activation to form a pallada( ii )cycle and subsequent amination with di- t -butyldiaziridinone.
ISSN:2052-4129
2052-4110
2052-4129
2052-4110
DOI:10.1039/D3QO01472J