Highly Sensitive Lifetime‐Based Luminescent Manometer on Mn4+ Luminescence in Sr4Al14O25 Mn4

Enabling remote and temperature‐independent pressure sensing based on luminescence kinetics holds significant potential for the development of a luminescence pressure sensor with a wide array of applications. To meet these requirements, in this work, a unique lifetime‐based luminescence manometer is demonstrated for which an increase in pressure results in an elongation of lifetime of 2E state of Mn4+ due to a change in the probability of radiative depopulation of the 2E level of Mn4+ ions with an unprecedentedly high sensitivity of 35% GPa−1. Furthermore, the pressure‐induced modification in the covalency of the Mn4+─O2− bond facilitates a manometer operating in spectral band shift and ratiometric modes with sensitivities of 26 cm−1 GPa−1 (1.2 nm GPa−1) and 24.8% GPa−1, respectively. This study firmly supports the belief that the distinct pressure‐dependent kinetics governing the depopulation of Mn4+ ions at the 2E level, along with the resulting advantageous manometric performance, will pave the way for a new research trajectory in luminescence manometry. The elongation of the luminescence kinetics of the 2E state of Mn4+ ions with increasing applied pressure in the Sr4Al14O25 Mn4+ enables the development of a lifetime‐based sensor with relative sensitivity as high as 35% GPa−1.