Palladium‐Catalyzed Enantioselective Indole Allylic Alkylation with Chiral Phosphoramidite‐Selenide‐Based Ligands

Palladium‐Catalyzed Enantioselective Indole Allylic Alkylation with Chiral Phosphoramidite‐Selenide‐Based Ligands

Environmental Engineering Organic Hybrid Functionalized Materials A Pd/phosphoramidite‐selenide‐catalyzed highly enantioselective C‐3 allylic alkylation with a wide range of indole nucleophiles has been developed, giving the corresponding products with up to 95 % yield and 99 % ee.

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Veröffentlicht in:European journal of organic chemistry 2024-01, Vol.27 (2)
Hauptverfasser: Feng, Bin, Zhang, Yun‐Fan, Li, Shan, You, Ge‐Yun, Xuan, Jun
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
Enantiomers
Environmental engineering
Nucleophiles
Palladium
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Zusammenfassung:Environmental Engineering Organic Hybrid Functionalized Materials A Pd/phosphoramidite‐selenide‐catalyzed highly enantioselective C‐3 allylic alkylation with a wide range of indole nucleophiles has been developed, giving the corresponding products with up to 95 % yield and 99 % ee.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.202300861