Inside Back Cover: Dual Catalysis of Gold Nanoclusters: Photocatalytic Cross‐Dehydrogenative Coupling by Cooperation of Superatomic Core and Molecularly Modified Staples (Angew. Chem. Int. Ed. 2/2024)

Dual catalysis of gold nanoclusters protected by thiolate ligands toward photocatalytic cross‐dehydrogenative coupling between aliphatic tertiary amines and terminal alkynes is reported by Katsuhiro Isozaki, Masaharu Nakamura et al. in their Research Article (e202312135). The cooperative catalytic p...

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Veröffentlicht in:Angewandte Chemie International Edition 2024-01, Vol.63 (2), p.n/a
Hauptverfasser: Isozaki, Katsuhiro, Iseri, Kenta, Saito, Ryohei, Ueda, Kyosuke, Nakamura, Masaharu
Format: Artikel
Sprache:eng
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Zusammenfassung:Dual catalysis of gold nanoclusters protected by thiolate ligands toward photocatalytic cross‐dehydrogenative coupling between aliphatic tertiary amines and terminal alkynes is reported by Katsuhiro Isozaki, Masaharu Nakamura et al. in their Research Article (e202312135). The cooperative catalytic properties of the superatomic core and gold‐thiolate staples were elucidated by mechanistic investigations and DFT calculations of ligand‐exchanged nanoclusters as the catalytically active intermediates.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202317977