Front Cover: Cation Radical Newman‐Kwart Rearrangement Enabled by Heterogeneous Photocatalysis under Mild Conditions (ChemCatChem 23/2023)

The Front Cover illustrates the conversion of O‐aryl thiocarbamates to the corresponding S‐aryl compounds (Newman‐Kwart rearrangement, NKR) as an interstellar journey in a spaceship. The voyage from the O‐aryl to the S‐aryl constellation is fueled by violet light and mediated by a titanium dioxide asteroid. In their Research Article, R. Francke co‐workers explored this photocatalytic approach (“P‐NKR”) as a mild and useful alternative to the conventional thermochemical method. More information can be found in the Research Article by R. Francke and co‐workers.