Hypervalent Iodine‐Mediated Alkyne Functionalization: Facile Access to Trifluoromethyl‐ and Pentafluoroethyl‐Substituted Thiazoles

The use of hypervalent iodine with Lewis acid provided alkyne trifluoromethylation and pentafluoroethylation to access trifluoro‐and pentafluoro‐substituted thiazoles. This simple and efficient method is compatible with a broad range of aryl‐ and alkyl‐substituted thiourea starting materials. Additi...

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Veröffentlicht in:	Asian journal of organic chemistry 2023-11, Vol.12 (11), p.n/a
Hauptverfasser:	Kwak, Yoonna, Choi, Ye Rin, Yu, Jaeni, Choi, Sungwook, Hong, Ki Bum
Format:	Artikel
Sprache:	eng
Schlagworte:	alkyne difunctionalization Alkynes copper catalysis Iodine Lewis acid Organic chemistry Substitutes thiazole synthesis thio-pentafluoroethylation thio-trifluoromethylation
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