Collaboratively enhancing electrochemical properties of LiNi0.83Co0.11Mn0.06O2 through doping and coating of quadrivalent elements

Ni-rich layered oxides (Ni ≥ 80%) with high energy density have become a mainstream cathode material for Li-ion batteries. However, irreversible phase transitions and interface instability are deep-seated challenges in commercializing Ni-rich materials. This study used a collaborative modification s...

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Veröffentlicht in:Rare metals 2023-12, Vol.42 (12), p.4103-4114
Hauptverfasser: Yu, Zhao-Zhe, Zhao, Gui-Quan, Ji, Fang-Li, Tong, Hao, Tong, Qi-Lin, Li, Hua-Cheng, Cheng, Yan
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Sprache:eng
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Zusammenfassung:Ni-rich layered oxides (Ni ≥ 80%) with high energy density have become a mainstream cathode material for Li-ion batteries. However, irreversible phase transitions and interface instability are deep-seated challenges in commercializing Ni-rich materials. This study used a collaborative modification strategy involving doping and coating with quadrivalent elements to construct Ni-rich materials. In particular, introducing tetravalent Zr makes the valence change of Ni (2+ to 4+) more accessible to complete spontaneously during the charging and discharging processes, which significantly suppresses the cationic mixing and irreversible phase transition (H2 ↔ H3). Combining the strategy of constructing CeO 2 coatings on the surface and interfacial spinel-like phases improves the Li + diffusion kinetics and interfacial stability. Simultaneously, part of the strongly oxidizing four-valence Ce 4+ diffuses to the surface layer, further increasing the average valence state of Ni. Therefore, LiNi 0.83 Co 0.11 Mn 0.06 O 2 (NCM)-Zr@Ce achieves 78.5% outstanding retention at 1.0C after 200 cycles within 3.0–4.3 V compared to unmodified NCM with 41.4% retention. The improved cyclic stability can be attributed to the collaborative modification strategy of the quadrivalent elements, which provides an effective synergistic modification strategy for developing high-performance Li-ion battery cathode materials. Graphical abstract
ISSN:1001-0521
1867-7185
DOI:10.1007/s12598-023-02356-3