Synthesis of a novel fluorinated polymer: poly(2-(tetrafluoro(trifluoromethyl)-λ6-sulfanyl)ethyl acrylate)

Tetrafluoro(trifluoromethyl)-λ 6 -sulfanylethyl acrylate, a novel acrylate monomer, was polymerized by initiation with azobisisobutyronitrile (AIBN) at 60 °C to form a soft gel. This novel fluorinated ester was prepared by condensation of excess acryloyl chloride with 2-(tetrafluoro(trifluoromethyl)...

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Veröffentlicht in:	Journal of polymer research 2023-12, Vol.30 (12), Article 443
Hauptverfasser:	Deng, Muqian, Welch, John T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Azobisisobutyronitrile Characterization and Evaluation of Materials Chemical synthesis Chemistry Chemistry and Materials Science Contact angle Fluoropolymers Industrial Chemistry/Chemical Engineering Original Paper Polymer Sciences Polymers Thermal decomposition
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Beschreibung
Zusammenfassung:	Tetrafluoro(trifluoromethyl)-λ 6 -sulfanylethyl acrylate, a novel acrylate monomer, was polymerized by initiation with azobisisobutyronitrile (AIBN) at 60 °C to form a soft gel. This novel fluorinated ester was prepared by condensation of excess acryloyl chloride with 2-(tetrafluoro(trifluoromethyl)-λ 6 -sulfanyl)ethan-1-ol. Thermal decomposition of the polymer begins at 180 °C. Aqueous wetting by static contact measurement yielded a contact angle of 98°.
ISSN:	1022-9760 1572-8935
DOI:	10.1007/s10965-023-03824-1