Alkene reactions with superoxide radical anions in flow electrochemistry

Alkene reactions with superoxide radical anions in flow electrochemistry

Alkenes were cleaved to ketones by using dioxygen in an electrochemical flow set-up. The pressurised system allowed efficient gas-liquid mixing with a stabilised flow. This mild and straightforward approach avoids the use of transition metals and harsh oxidants. Molecular oxygen is used under biphas...

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Veröffentlicht in:Faraday discussions 2023-10, Vol.247, p.297-31
Hauptverfasser: Ali, Rojan, Patra, Tuhin, Wirth, Thomas
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Electrochemistry
Ketones
Oxidizing agents
Transition metals
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Zusammenfassung:Alkenes were cleaved to ketones by using dioxygen in an electrochemical flow set-up. The pressurised system allowed efficient gas-liquid mixing with a stabilised flow. This mild and straightforward approach avoids the use of transition metals and harsh oxidants. Molecular oxygen is used under biphasic electrochemical flow conditions to cleave alkenes.
ISSN:1359-6640
1364-5498
DOI:10.1039/d3fd00050h