Enhanced Performance of Bimetallic Pd-based Electrocatalysts for Formic Acid Oxidation
Pd-based catalysts supported on high-surface-area carbon are widely used in formic acid fuel cells. The composition, structure, and support can be modified to maximize the capabilities of Pd-based catalysts in terms of catalytic activity, durability, and cost. Various studies have investigated tunin...
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Veröffentlicht in: | Topics in catalysis 2023-11, Vol.66 (19-20), p.1608-1618 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Pd-based catalysts supported on high-surface-area carbon are widely used in formic acid fuel cells. The composition, structure, and support can be modified to maximize the capabilities of Pd-based catalysts in terms of catalytic activity, durability, and cost. Various studies have investigated tuning the properties of Pd-based catalysts by alloying Pd with other metals. In this study, Cr, Ni, Cu, and Zn were incorporated into Pd-based catalysts. First, the effects of mole ratios were studied between Pd and the metals. The Pd
n
Ni ratios on a reduced graphene oxide support (Pd
n
Ni/rGO) were prepared using the one-pot method without the use of any surfactants. All obtained rGO-supported Pd
n
Ni catalysts (
n
= 1, 2, 4, with diameter of 5 nm) were used for the electrocatalytic oxidation of formic acid. The electro-oxidation measurements revealed that the Pd
n
Ni/rGO samples had superior electrocatalytic performance both in current densities and stabilities for formic acid oxidation (FAO) compared to Pd/rGO. Furthermore, Pd
4
Ni/rGO had greater electrocatalytic activity than the other Pd
n
Ni/rGO samples. In addition, with the same mole ratio of metals, Pd
4
Cr/rGO had higher efficiency toward FAO than the other series in the order: Pd
4
Cr/rGO > Pd
4
Ni/rGO > Pd
4
Cu/rGO > Pd
4
Zn/rGO. |
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ISSN: | 1022-5528 1572-9028 |
DOI: | 10.1007/s11244-023-01821-8 |