Bis(chlorido)tin(IV) meso ‐substituted Porphyrins‐Characterization and Solubility

Bis(chlorido)tin(IV) meso ‐substituted Porphyrins‐Characterization and Solubility

Investigation of the solubility behavior of para ‐substituted (H, Me, t ‐Bu, n ‐Bu) meso ‐tetraarylporphyrins as well as meso ‐tetraalkylporphyrins (Me, n ‐Pr, n ‐Bu) were performed. An increase of solubility in chloroform and benzene is detected according to the higher functionality in para positio...

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Veröffentlicht in:European journal of inorganic chemistry 2023-10, Vol.26 (28)
Hauptverfasser: Grössl, Doris M., Hafner, Anna‐Viktoria, Fischer, Roland C., Saf, Robert, Torvisco, Ana, Uhlig, Frank
Format: Artikel
Sprache:eng
Schlagworte:
Benzene
Chloroform
Inorganic chemistry
NMR
Nuclear magnetic resonance
Porphyrins
Single crystals
Solubility
Substitutes
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Zusammenfassung:Investigation of the solubility behavior of para ‐substituted (H, Me, t ‐Bu, n ‐Bu) meso ‐tetraarylporphyrins as well as meso ‐tetraalkylporphyrins (Me, n ‐Pr, n ‐Bu) were performed. An increase of solubility in chloroform and benzene is detected according to the higher functionality in para position of the phenyl ring for meso ‐tetraarylporphyrins or in meso position on meso ‐tetraalkylporphyrins. Furthermore, the series of bis(chlorido)tin(IV) meso ‐tetraarylporphyrin and bis(chlorido)tin(IV) meso ‐tetraalkylporphyrin was investigated via UV/Vis spectroscopy, 119 Sn‐NMR and single crystal X‐ray diffraction.
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.202300286