Synthesis of functionalized furan-containing phosphonous and phosphinic acids

Synthesis of functionalized furan-containing phosphonous and phosphinic acids

A convenient synthesis of functionalized furan-containing phosphonous and phosphinic acids has been developed. The radical addition of bis(trimethylsiloxy)phosphine to 2-vinylfuran and trimethylsilyl 3-(2-furyl)acrylate proceeds regioselectively to afford new 2-furyl-substituted alkylphosphonites, t...

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Veröffentlicht in:Russian chemical bulletin 2023-09, Vol.72 (9), p.2138-2147
Hauptverfasser: Prishchenko, A. A., Livantsov, M. V., Novikova, O. P., Livantsova, L. I., Baranin, S. V., Bubnov, Yu. N.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
Phosphines
Synthesis
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Beschreibung
Zusammenfassung:A convenient synthesis of functionalized furan-containing phosphonous and phosphinic acids has been developed. The radical addition of bis(trimethylsiloxy)phosphine to 2-vinylfuran and trimethylsilyl 3-(2-furyl)acrylate proceeds regioselectively to afford new 2-furyl-substituted alkylphosphonites, the subsequent aminomethylation and carboxyethylation of which give various target phosphinic acids.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-023-4009-5