Inside Cover: Mechanistic Understanding of Efficient Polyethylene Hydrocracking over Two‐Dimensional Platinum‐Anchored Tungsten Trioxide (Angew. Chem. Int. Ed. 40/2023)

Chemical upcycling of high‐density polyethylene at low temperatures remains a significant challenge. In their Research Article (e202305644), Qingyue Wang, Pingwei Liu and co‐workers report a two‐dimensional platinum‐anchored tungsten trioxide catalyst with abundant vacancies and acidic sites that co...

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Veröffentlicht in:Angewandte Chemie International Edition 2023-10, Vol.62 (40), p.n/a
Hauptverfasser: Zhou, Qimin, Wang, Deliang, Wang, Qingyue, He, Kailin, Lim, Khak Ho, Yang, Xuan, Wang, Wen‐Jun, Li, Bo‐Geng, Liu, Pingwei
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Sprache:eng
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Zusammenfassung:Chemical upcycling of high‐density polyethylene at low temperatures remains a significant challenge. In their Research Article (e202305644), Qingyue Wang, Pingwei Liu and co‐workers report a two‐dimensional platinum‐anchored tungsten trioxide catalyst with abundant vacancies and acidic sites that converts polyethylene effectively to fuel. A quasi‐operando spectroscopic study reveals that polymer chains are activated by forming olefinic intermediates, and then hydrocracked by the dissociated hydrogen on two‐dimensional catalyst to form fuel alkanes.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202310566