Concept of Carbide Compaction of Mixed Uranium-Plutonium Fuel

The Fermi level in uranium dioxide with band gap ε g = 2.1 eV is a logarithmic identifier of the oxidation state of the dioxide and serves as a measure of the electron occupation of the local energy levels in the band gap. An impurity additive in the form of a trivalent metal is required in order to...

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Veröffentlicht in:Atomic energy (New York, N.Y.) N.Y.), 2023-02, Vol.133 (4), p.196-199
1. Verfasser: Shimkevich, A. L
Format: Artikel
Sprache:eng
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Zusammenfassung:The Fermi level in uranium dioxide with band gap ε g = 2.1 eV is a logarithmic identifier of the oxidation state of the dioxide and serves as a measure of the electron occupation of the local energy levels in the band gap. An impurity additive in the form of a trivalent metal is required in order to transfer the dioxide into a stable hypostoichiometric state with a high density of oxygen vacancies. This can be accomplished in mixed uranium-plutonium fuel, which is then easily compacted with dispersed particles of uranium carbide.
ISSN:1063-4258
1573-8205
DOI:10.1007/s10512-023-00995-4