Cover Feature: Unexpected Coexisting Solid Solutions in the Quasi‐Binary Ag(II)F2/Cu(II)F2 Phase Diagram

In the presence of F2 overpressure, at elevated temperature, and despite the similarity of their crystal structures, CuF2 and AgF2 unexpectedly form two distinct solid solutions, (Cu1−xAgx)F2 and (Ag1−xCux)F2. Each phase shows different mutual solubility of Cu2+ and Ag2+ (shown as yellow and violet...

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Veröffentlicht in:	Chemistry : a European journal 2023-09, Vol.29 (52)
Hauptverfasser:	Jezierski, D, Koteras, K, Domański, M, Połczyński, P, Mazej, Z, Lorenzana, J, Grochala, W
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Copper Copper fluorides High temperature Magnetic properties Overpressure Phase diagrams Solid solutions
Online-Zugang:	Volltext
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