1,1,3,3-Tetramethylguanidine-iodine system as an efficient catalyst for CO2 addition to oxiranes
A catalytic system obtained by mixing 1,1,3,3-tetramethylguanidine and iodine was tested for the reaction of monosubstituted oxiranes with CO 2 affording organic cyclic carbonates. The catalyst turned out to be effective not only for substrates with substituents, which have different sizes and donor...
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| Veröffentlicht in: | Russian chemical bulletin 2023-08, Vol.72 (8), p.1933-1935 |
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| container_end_page | 1935 |
|---|---|
| container_issue | 8 |
| container_start_page | 1933 |
| container_title | Russian chemical bulletin |
| container_volume | 72 |
| creator | Lyubimov, S. E. Cherkasova, P. V. |
| description | A catalytic system obtained by mixing 1,1,3,3-tetramethylguanidine and iodine was tested for the reaction of monosubstituted oxiranes with CO
2
affording organic cyclic carbonates. The catalyst turned out to be effective not only for substrates with substituents, which have different sizes and donor-acceptor properties, but also in the case of bis-oxiranes. |
| doi_str_mv | 10.1007/s11172-023-3979-7 |
| format | Article |
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| ispartof | Russian chemical bulletin, 2023-08, Vol.72 (8), p.1933-1935 |
| issn | 1066-5285 1573-9171 |
| language | eng |
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| subjects | Brief Communications Carbon dioxide Carbonates Catalysts Chemistry Chemistry and Materials Science Chemistry/Food Science Inorganic Chemistry Iodine Organic Chemistry Substrates |
| title | 1,1,3,3-Tetramethylguanidine-iodine system as an efficient catalyst for CO2 addition to oxiranes |
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