4-[4-Bromo-2-(2-phenyldiazenyl)phenoxy]phthalonitrile and related magnesium and zinc phthalocyanines: synthesis and properties

4-[4-Bromo-2-(2-phenyldiazenyl)phenoxy]phthalonitrile and related magnesium and zinc phthalocyanines: synthesis and properties

4-[4-Bromo-2-(2-phenyldiazenyl)phenoxy]phthalonitrile was obtained by the reaction of 4-nitrophthalonitrile and sodium 4-bromo-2-(2-phenyldiazenyl)phenolate. Magnesium and zinc phthalocyaninates were synthesized by the template condensation of the corresponding metals with phthalonitrile. The lumine...

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Veröffentlicht in:Russian chemical bulletin 2023-08, Vol.72 (8), p.1753-1759
Hauptverfasser: Bychkova, A. N., Kazaryan, K. Yu, Eremeev, I. E., Skvortsov, I. A., Tikhomirova, T. V., Vashurin, A. S.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Luminescence
Magnesium
Optical properties
Organic Chemistry
Singlet oxygen
Synthesis
Zinc
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Zusammenfassung:4-[4-Bromo-2-(2-phenyldiazenyl)phenoxy]phthalonitrile was obtained by the reaction of 4-nitrophthalonitrile and sodium 4-bromo-2-(2-phenyldiazenyl)phenolate. Magnesium and zinc phthalocyaninates were synthesized by the template condensation of the corresponding metals with phthalonitrile. The luminescence properties and photosensitization of singlet oxygen for the synthesized complexes were studied.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-023-3957-0