Synthesis, Structure, and Properties of the Iron Nitrosyl Complex with 2-Ethyl-4-pyridinecarbothioamide

Synthesis, Structure, and Properties of the Iron Nitrosyl Complex with 2-Ethyl-4-pyridinecarbothioamide

The synthesis and data on the physicochemical characteristics and biological activity of the new iron nitrosyl complex (Q + ) 2 [Fe 2 (S 2 O 3 ) 2 (NO) 4 ] 2– ( I ), where Q + is protonated 2-ethyl-4-pyridinecarbothioamide (C 8 H 11 N 2 S), are presented. The structure and properties of the complex...

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Veröffentlicht in:Russian journal of coordination chemistry 2023-09, Vol.49 (9), p.542-554
Hauptverfasser: Sanina, N. A., Shilov, G. V., Ovanesyan, N. S., Mumyatova, V. A., Balakina, A. A., Terent’ev, A. A., Pokidova, O. V., Aldoshin, S. M.
Format: Artikel
Sprache:eng
Schlagworte:
Biological activity
Chemistry
Chemistry and Materials Science
Electrical measurement
Infrared spectroscopy
Inorganic Chemistry
Iron
Mossbauer spectroscopy
Physical Chemistry
Synthesis
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Zusammenfassung:The synthesis and data on the physicochemical characteristics and biological activity of the new iron nitrosyl complex (Q + ) 2 [Fe 2 (S 2 O 3 ) 2 (NO) 4 ] 2– ( I ), where Q + is protonated 2-ethyl-4-pyridinecarbothioamide (C 8 H 11 N 2 S), are presented. The structure and properties of the complex were studied by X-ray diffraction, elemental analysis, IR and Mössbauer spectroscopy, and amperometry. The complex showed antibacterial activity and efficiently inhibited cyclic guanosine monophosphate phosphodiesterase (cGMP PDE), which may suggest its antihypertensive, anti-aggregation, and vasodilator activities.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328423600523