Cover Feature: Origin of the Bürgi‐Dunitz Angle (ChemPhysChem 17/2023)

Cover Feature: Origin of the Bürgi‐Dunitz Angle (ChemPhysChem 17/2023)

The Cover Feature shows different approaches of a nucleophile (cyanide) to the carbonyl group of acetone and highlights the preferred obtuse, Bürgi‐Dunitz trajectory. The factors leading to the Bürgi‐Dunitz angle are revealed in the Research Article by Israel Fernández and co‐workers.

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Veröffentlicht in:Chemphyschem 2023-09, Vol.24 (17), p.n/a
Hauptverfasser: Rodríguez, Humberto A., Bickelhaupt, F. Matthias, Fernández, Israel
Format: Artikel
Sprache:eng
Schlagworte:
Bürgi-Dunitz angle
carbonyl
Carbonyl groups
Carbonyls
density functional calculations
Nucleophiles
nucleophilic addition
Pauli repulsion
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Beschreibung
Zusammenfassung:The Cover Feature shows different approaches of a nucleophile (cyanide) to the carbonyl group of acetone and highlights the preferred obtuse, Bürgi‐Dunitz trajectory. The factors leading to the Bürgi‐Dunitz angle are revealed in the Research Article by Israel Fernández and co‐workers.
ISSN:1439-4235
1439-7641
DOI:10.1002/cphc.202300541